Based on field surveys, soil samples were collected at the YPC site, Yuzhou City, Henan Province for analysis of contents of major and trace elements and their variations with XRF and comparison with the curves of magnetic susceptibility, pH value distribution, loss on ignition and particle-size distribution. It was concluded that the dust source of loess in the upper reaches of the Huaihe River Basin was different from that in the Loess Plateau. And the Holocene pedogenic environmental changes in the upper reaches of the Huaihe River Basin were revealed.